The world number 1 and number 2 eased past their respective semi-final opponents – Taylor Fritz and Novak Djokovic – both with 6-4 6-2 wins.
Alcaraz admitted that he was not fully fit at the new exhibition after injuring his ankle against Sebastien Baez in Tokyo.
Sinner, meanwhile, gave Dutchman Talon Greekpoor a walkover in the second round of the Shanghai Masters, after he suffered severe cramps halfway through the match due to the extreme heat.
The most recent meeting between the pair came in the US Open final, where Alcaraz defeated the Italian in four sets.
Before that, Sinner had lost the final against Cincinnati when he was 5-0 down against the Spaniard due to illness.
Alcaraz has dominated the pair’s head-to-head matches and leads 10-5, although Sinner has usurped the 22-year-old at Wimbledon this year to claim a first title on grass.
What time is Carlos Alcaraz vs. Jannik Sinner?
The final of the Six Kings Slam will take place on Saturday, October 18.
The match doesn’t start until 7pm BST, scheduled after the third-place match between Fritz and Djokovic, which starts at 5pm BST.
How to watch Carlos Alcaraz vs. Jannik Sinner
Live stream: This tournament will be streamed exclusively on Netflix. It is not a pay-per-view event and those with a Netflix subscription can stream it live.
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